Exposure apparatus, exposure method, and device fabrication method

ABSTRACT

An exposure apparatus forms an immersion area by supplying a liquid onto a part of a substrate, and forms a prescribed pattern on the substrate through the liquid. A spare immersion area, which is capable of holding part of the liquid on the substrate, is formed at the outer circumference of the immersion area. It is possible to prevent the separation of the liquid, which is disposed between a lower surface of a projection optical system and a substrate surface, from the lower surface of the projection optical system in accordance with the relative movement of the projection optical system and the substrate.

CROSS-REFERENCE TO RELATED APPLICATION

This is a Continuation Application of International Application No.PCT/JP2004/015796, filed Oct. 25, 2004, which claims priority toJapanese Patent Application No. 2003-366914 (filed Oct. 28, 2003). Thecontents of the aforementioned application are incorporated herein byreference.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention is a technology that relates to an exposureapparatus used in the transfer process of the lithographic process formanufacturing highly integrated semiconductor circuit devices.

2. Description of the Related Art

Semiconductor devices and liquid crystal display devices are fabricatedby a so-called photolithography technique, wherein a pattern formed on amask is transferred onto a photosensitive substrate. An exposureapparatus used in this photolithographic process has a mask stage thatsupports the mask, and a substrate stage that supports the substrate,and transfers the pattern of the mask onto the substrate through aprojection optical system while successively moving the mask stage andthe substrate stage.

There has been demanded in recent years for higher resolution projectionoptical systems in order to handle the much higher levels of integrationof device patterns. The shorter the exposure wavelength used and thelarger the numerical aperture of the projection optical system, thehigher the resolution of the projection optical system. Consequently,the exposure wavelength used in exposure apparatuses has shortened yearby year, and the numerical aperture of projection optical systems hasincreased. Furthermore, the mainstream exposure wavelength is currentlythe 248 mn assigned to KrF excimer laser, but an even shorter wavelength193 nm assigned to ArF excimer laser is also being commercialized. Inaddition, as with resolution, the depth of focus (DOF) is important whenperforming exposure. The following equations express the resolution Rand the depth of focus δ, respectively.R=k ₁ ·λ/NA  (1)δ=±k ₂ ·/NA ²  (2)

Therein, λ is the exposure wavelength, NA is the numerical aperture ofthe projection optical system, and k₁ and k₂ are the processcoefficients. Equations (1) and (2) teach that if the exposurewavelength λ is shortened and the numerical aperture NA is increased inorder to enhance the resolution R, then the depth of focus δ decreases.

If the depth of focus δ becomes excessively narrow, then it will becomedifficult to make the surface of the substrate coincide with the imageplane of the projection optical system, and there will be a risk ofinsufficient margin during the exposure operation. Accordingly, a liquidimmersion method has been proposed, as disclosed in, for example,Reference Document 1 (PCT International Publication WO99/49504), as amethod to substantially shorten the exposure wavelength and increase thedepth of focus. In this liquid immersion method, a gap between the lowersurface of the projection optical system and the surface of thesubstrate is filled with a liquid, such as water or an organic solvent,thus taking advantage of the fact that the wavelength of the exposurelight in a liquid is 1/n that of in air (where n is the refractive indexof the liquid, normally about 1.2 to 1.6), thereby improving theresolution as well as increasing the depth of focus by approximately ntimes.

As far as is permitted, the disclosure of the above PCT InternationalPublication is hereby incorporated by reference.

Incidentally, when the projection optical system and the substrate moverelatively to one another, the liquid in the immersion area between theprojection optical system and the substrate surface begins to move whilebeing dragged in the direction of the movement of the substrate. Inparticular, a phenomenon occurs wherein, if the relative movement occursat high speed in order to improve throughput, then the liquid separatesfrom the lower surface of the projection optical system. Consequently,the separation of the liquid from the lower surface of the projectionoptical system is prevented by increasing the flow rate of the liquidsupplied to the immersion area Nevertheless, if the flow rate of theliquid is increased, then there is a problem in that the generation ofvibrations and bubbles in accordance with the movement of the liquidhinders the formation of the circuit pattern.

SUMMARY OF THE INVENTION

The present invention was made considering the circumstances discussedabove, and it is therefore an object of the present invention to providean exposure apparatus, an exposure method, and a device fabricationmethod that can prevent a liquid, which is disposed between the lowersurface of a projection optical system and the surface of a substrate,from separating from the lower surface of the projection optical systemin accordance with relative movement of the projection optical systemand the substrate.

The exposure apparatus, the exposure method, and the device fabricationmethod according to the present invention adopt the following means inorder to solve the abovementioned problems.

The first aspect is an exposure apparatus (EX) that forms an immersionarea (AR2) by supplying a liquid (L) onto a part of a substrate (W), andforms a prescribed pattern on the substrate through the liquid, whereina spare immersion area (AR3), which is capable of holding part of theliquid on the substrate, is formed at an outer circumference of theimmersion area.

In addition, the exposure apparatus may comprise a projection opticalsystem (PL), wherein the prescribed pattern is formed by exposing thesubstrate through the projection optical system and the liquid (L)positioned between the projection optical system and the substrate (W);and when the projection optical system and the substrate move relativelyto one another, part of the liquid of the immersion area (AR2) can moveto the spare immersion area (AR3), and part of the liquid of the spareimmersion area also moves to the immersion area, in accordance with adirection of the relative movement.

In addition, the liquid (L) of the spare immersion area (AR3) may beheld by a liquid holding part (80, 90) provided in a manner such thatthe liquid holding part is spaced apart by a prescribed distance fromthe outer circumference of the immersion area (AR2).

In addition, the liquid holding part (80, 90) may be provided at a outercircumference of a substantially annular groove part (70) formed in alower surface (PLa) of the projection optical system (PL).

The liquid holding part (80, 90) can comprise, for example, asubstantially annular wall part (80).

In addition, the liquid holding part (80, 90) can also comprise aplurality of projection parts (90), which are disposed substantiallyannularly.

In addition, the liquid holding part (80, 90) is made of an elasticmaterial.

In addition, a plurality of the liquid holding parts (80, 90) isprovided.

In addition, a lyophilic area is formed in the liquid holding part (80,90).

In addition, a liquid recovery part (24), which recovers the liquid, isprovided at an outer circumference of the liquid holding part (80, 90).

In addition, the liquid recovery part (23), which recovers the liquid(L), is provided to a bottom surface (70 b) of the groove part (70).

An exposure apparatus (EX) is provided, which exposes a substrate (W) byfilling a gap between the substrate (W) and a projection optical system(PL) with a liquid (L), and projecting a pattern image onto thesubstrate (W) through the projection optical system (PL) and the liquid(L), wherein:

an immersion area (AR2) that includes a projection area (AR1) of theprojection optical system (PL) and that is continually filled with theliquid (L) during an exposure operation, and a spare immersion area(AR3) provided to an outer circumference of the immersion area (AR2) areformed; and

a first area wherein the liquid (L) exists and a second area wherein theliquid (L) does not exist are formed in the spare immersion area (AR3)during the exposure operation, and the positions of the first area andthe second area inside the spare immersion area (AR3) change inaccordance with the exposure operation.

The present invention also provides an exposure apparatus (EX) thatexposes a substrate by forming an immersion area by supplying a liquid(L) onto part of the substrate (W), and projecting a pattern image ontothe substrate through the liquid, wherein the immersion area has a firstarea (AR2) that includes an area wherein the pattern image is projected;and a second area (AR3), which is proximate to the first area, whereinthe liquid is capable of moving to and from the first area.

The present invention further provides an exposure apparatus (EX) thatexposes a substrate by forming an immersion area by supplying a liquid(L) onto a part of the substrate (W), and projecting a pattern imageonto the substrate through the liquid, the apparatus comprising: aliquid holding member (60) for forming the immersion area, wherein theimmersion area includes a first area (AR2), wherein the liquid iscontinually held during exposure, and a second area (AR3), which iscapable of moving with respect to the liquid immersion holding memberduring the exposure.

The second aspect is an exposure method for exposing a substrate (W) byforming an immersion area (AR2) by supplying a liquid (L) onto part of asubstrate (W), which includes a projection area (AR1) of a projectionoptical system (PL), and projecting a pattern image onto the substrate(W) through the projection optical system (PL) and the liquid (L)positioned between the projection optical system (PL) and the substrate(W), the method comprising the step of disposing part of the liquid (L)supplied onto the substrate (W) in a spare immersion area (AR3) that isformed at an outer circumference of the immersion area (AR2).

In addition, the step of disposing part of the liquid (L) in the spareimmersion area (AR3) may be performed prior to exposure of the substrate(W).

In addition, there a further step may be provided, which supplies andrecovers the liquid (L) to and from the immersion area (AR2) and thespare immersion area (AR3), wherein the amount of the liquid supplied tothe immersion area (AR2) and the spare immersion area (AR3) is greaterthan the amount of the liquid recovered.

The third aspect is a device fabrication method that includes alithographic process, wherein an exposure apparatus (EX) according tothe first aspect, or an exposure method according to second aspect, isused in the lithographic process.

The present invention can achieve the following effects.

The first aspect is an exposure apparatus that forms an immersion areaby supplying a liquid onto a part of a substrate, and forms a prescribedpattern on the substrate through the liquid, wherein a spare immersionarea, which is capable of holding part of the liquid on the substrate,is formed at the outer circumference of the immersion area. Thereby, thespare immersion area that further holds the liquid at the outercircumference of the immersion area is formed; therefore, if, forexample, the amount of the liquid in the immersion area has becomeinsufficient, the liquid in the spare immersion area is supplied to theimmersion area and it is therefore possible to avoid an exposure failuredue to an insufficient amount of the liquid.

In addition, the exposure apparatus may have a projection opticalsystem, wherein the prescribed pattern is formed by exposing thesubstrate through the projection optical system and the liquidpositioned between the projection optical system and the substrate; and,when the projection optical system and the substrate move relatively toone another, part of the liquid of the immersion area moves to the spareimmersion area, and vice versa, in accordance with the direction of therelative movement; therefore, even if the liquid of the immersion areabegins to move from the lower surface of the projection optical systemin accordance with the relative movement of the projection opticalsystem and the substrate, the liquid of the spare immersion area issupplied to the lower surface of the projection optical system, and itis therefore possible to continually fill the area of the lower surfaceof the projection optical system with the liquid, without performing aspecial process.

In addition, the liquid of the spare immersion area is held by a liquidholding part, which is provided at the outer circumference of theimmersion area, spaced apart by a prescribed distance; therefore,because the spare immersion area can be reliably formed at the outercircumference of the immersion area by a simple mechanism, it ispossible to suppress an increase in the cost of the apparatus.

In addition, the liquid holding part is provided at the outercircumference of a substantially annular groove part formed in the lowersurface of the projection optical system; therefore, it is possible,with a simple structure, to physically isolate the two areas that holdthe liquid, i.e., the lower surface of the projection optical system andthe liquid holding part; further, the immersion area and the spareimmersion area can be easily formed.

In addition, the liquid holding part has a substantially annular wallpart, and therefore can hold the liquid at the outer circumference ofthe immersion area with a simple structure.

In addition, the liquid holding part has a plurality of projectionparts, which are disposed substantially annularly, and can thereforehold the liquid at the outer circumference of the immersion area with asimple structure.

In addition, the liquid holding part is made of an elastic material, andit is therefore possible to minimize damage to the substrate, and thelike, when interference occurs between the liquid holding part and thesubstrate, and the like.

In addition, a plurality of the liquid holding parts is provided, andtherefore the liquid can be held more reliably, leakage of the liquid tothe outer side of the spare immersion area can be prevented, andproblems with the exposure apparatus can be prevented.

In addition, a lyophilic area is formed in the liquid holding part,which makes it easier to form a bond with the molecules of the liquid,thereby strengthening the adhesion to the liquid and increasing theliquid holding power. Thereby, leakage of the liquid to the outer sideof the spare immersion area can be prevented, and problems with theexposure apparatus can be prevented.

In addition, a liquid recovery part, which recovers the liquid, isprovided at the outer circumference of the liquid holding part, andtherefore the liquid that leaks to the outer side of the spare immersionarea can be recovered, and problems with the exposure apparatus can beprevented.

In addition, the liquid recovery part, which recovers the liquid, isprovided to the bottom surface of the groove part, and therefore it iseasier to recover the liquid of the immersion area and the spareimmersion area, leakage of the liquid to the outer side of the spareimmersion area can be prevented, and problems with the exposureapparatus can be prevented.

In addition, an exposure apparatus that exposes a substrate by filling agap between the substrate and a projection optical system with a liquid,and projecting a pattern image onto the substrate through the projectionoptical system and the liquid, has: an immersion area that includes aprojection area of the projection optical system and that is continuallyfilled with the liquid during the exposure operation; and a spareimmersion area that is provided to the outer circumference of theimmersion area; wherein, a first area wherein the liquid exists and asecond area wherein the liquid does not exist are formed in the spareimmersion area during the exposure, and the positions of the first areaand the second area inside the spare immersion area change in accordancewith the exposure operation. Thereby, if the position of the liquid ofthe spare immersion area formed at the outer circumference of theimmersion area is changed in accordance with the movement of thesubstrate, then the liquid of the spare immersion area can be suppliedto the immersion area if, for example, the amount of the liquid of theimmersion area has become insufficient; on the other hand, the immersionarea can be continually filled with the liquid by recovering the liquidthat leaks out from the immersion area.

The second aspect is an exposure method that exposes a substrate byforming an immersion area by supplying a liquid onto part of a substratethat includes a projection area of a projection optical system, andprojecting a pattern image onto the substrate through the projectionoptical system and the liquid positioned between the projection opticalsystem and the substrate, comprising a step of disposing part of theliquid supplied onto the substrate in a spare immersion area that isformed at the outer circumference of the immersion area. Thereby, whenthe amount of the liquid in the immersion area has become insufficient,the liquid of the spare immersion area is supplied to the immersionarea, and therefore it is possible to avoid an exposure failure becauseof an insufficient amount of the liquid, and to improve yield.

In addition, the process of disposing part of the liquid in the spareimmersion area is performed prior to the exposure of the substrate, andtherefore it is possible to avoid an exposure failure because of aninsufficient amount of the liquid from the start of the exposureprocess, and to improve yield.

In addition, a process is included that supplies and recovers the liquidto and from the immersion area and the spare immersion area, wherein theamount of the liquid supplied to the immersion area and the spareimmersion area is greater than the amount of liquid recovered;therefore, although part of the liquid overflows out of the immersionarea, it is held by the spare immersion area, and it is thereforepossible to avoid problems with the exposure apparatus due to theleakage of the liquid. Accordingly, there is no longer a need toprecisely control the amount of the liquid in the immersion area so thatit is constant, which simplifies control of the flow rate.

The third aspect is a device fabrication method that includes alithographic process, wherein an exposure apparatus according to thefirst aspect, or an exposure method according to second aspect, is usedin the lithographic process. Thereby, exposure failures are suppressedand yield can be improved. Accordingly, the fabrication cost of devicescan be reduced.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic block diagram that depicts an exposure apparatusaccording to the present invention.

FIG. 2A is an enlarged view that depicts the vicinity of an immersionarea, and is a side cross sectional view that includes a projectionoptical system PL, and FIG. 2B depicts the lower surface side of theprojection optical system PL, viewed from the wafer stage WST side.

FIG. 3A is an perspective view of the lower surface side of theprojection optical system, viewed from the wafer stage side, and FIG. 3Bis an enlarged view that depicts the vicinity of the immersion areaaccording to a modified example, and is a side cross sectional view thatincludes the projection optical system PL.

FIG. 4 depicts an example of the shape of the liquid disposed in theimmersion area and the spare immersion area at the start of exposure.

FIG. 5 depicts an aspect of the movement of the liquid in the immersionarea and the spare immersion area.

FIG. 6 depicts a modified example of a groove part.

FIG. 7A depicts a modified example of wall parts, and FIG. 7B depictsanother modified example of wall parts.

FIG. 8A depicts an example wherein a liquid recovery mechanism, whichrecovers the liquid at the bottom surface of the groove part, isprovided, and is a side cross sectional view that includes theprojection optical system PL, and FIG. 8B depicts the lower surface sideof the projection optical system PL in the same example, viewed from thewafer stage WST side.

FIG. 9A depicts an example wherein a plurality of wall parts and thelike, which form the spare immersion area, is provided, and is a sidecross sectional view that includes the projection optical system PL, andFIG. 9B depicts the lower surface side of the projection optical systemPL in the same example, viewed from the wafer stage WST side.

FIG. 10 is a flow chart diagram that depicts one example of a processfor manufacturing a semiconductor device.

DETAILED DESCRIPTION OF THE INVENTION

The following explains the embodiments of an exposure apparatus, anexposure method, and a device fabrication method according to thepresent invention, referencing the drawings.

FIG. 1 is a schematic block diagram that depicts one embodiment of theexposure apparatus according to the present invention. In FIG. 1, anexposure apparatus EX has: a reticule stage RST that supports a reticle(mask) R in which a device pattern is formed; a wafer stage WST thatsupports a wafer (substrate) W coated with a photoresist, which is aphotosensitive material; an illumination optical system IL thatilluminates the reticle R supported by the reticle stage RST withexposure light EL; a projection optical system PL that projects theimage of a pattern AR of the reticle R, which is illuminated by theexposure light EL, onto the wafer W supported by the wafer stage WST, soas to expose the wafer W; and a control apparatus CONT that performssupervisory control of the operation of the entire exposure apparatusEX.

Here, the present embodiment explains, as an example, a case of using ascanning type exposure apparatus (a so-called scanning stepper) as theexposure apparatus EX to expose the wafer W with the pattern AR formedin the reticle R, while synchronously moving the reticle R and the waferW in mutually different orientations (reverse directions) in theirrespective scanning directions. In addition, in the explanation below,the direction that coincides with the optical axis AX of the projectionoptical system PL is the Z axial direction, the (scanning) direction inwhich the reticle R and the wafer W synchronously move within the planeperpendicular to the Z axial direction is the X axial direction, and thedirection perpendicular to the Z axial direction and the X axialdirection (non-scanning direction) is the Y axial direction.

Furthermore, the directions around the X, Y and Z axes are the θX, θYand θZ directions, respectively.

In addition, the exposure apparatus EX is an immersion exposureapparatus that adopts the liquid immersion method in order tosubstantially shorten the exposure wavelength, improve resolution, aswell as substantially increase the depth of focus, and has a liquidsupply mechanism 10 that supplies a liquid L onto the wafer W, and aliquid recovery mechanism 20 that recovers the liquid L on the wafer W.

Furthermore, the exposure apparatus EX, at least while transferring theimage of the pattern AR of the reticle R onto the wafer W, forms, withthe liquid L supplied from the liquid supply mechanism 10, an immersionarea AR2 and a spare immersion area AR3 on part of the wafer W thatincludes the projection area AR1 of the projection optical system PL.Specifically, the exposure apparatus EX forms the immersion area AR2 byfilling a gap between the optical element 2 at the tip (lower end) partof the projection optical system PL and the surface of the wafer W withthe liquid L. In addition, the exposure apparatus EX forms the spareimmersion area AR3 by also providing the liquid L at the outercircumference of the optical element 2 at the tip part of the projectionoptical system PL. Furthermore, the exposure apparatus EX exposes thewafer W by projecting the image of the pattern AR of the reticle R ontothe wafer W through the projection optical system PL and the liquid L ofthe immersion area AR2.

Furthermore, by supplying the liquid L from the liquid supply mechanism10 to the immersion area AR2 and the spare immersion area AR3, as wellas by recovering the liquid L by the liquid recovery mechanism 20 fromthe immersion area AR2 and the spare immersion area AR3, the liquid L ofthe immersion area AR2 and the spare immersion area AR3 continuallycirculates; further, the contamination of the liquid L is strictlyprevented, the temperature of the liquid L is strictly controlled, etc.

In addition, pure water is used as the liquid L in the presentembodiment. Pure water can transmit the deep ultraviolet light (DUVlight) such as KrF excimer laser light (248 nm wavelength), and thebright lines (g line, h line, and i line) in the ultraviolet regionemitted from, for example, a mercury lamp, as well as vacuum ultravioletlight (VUV light), such as ArF excimer laser light (193 nm wavelength).

The illumination optical system IL illuminates the reticle R, which issupported by the reticle stage RST, with the exposure light EL and has:an exposure light source; an optical integrator that uniformizes theintensity or illuminance of the luminous flux emitted from the exposurelight source; a condenser lens that condenses the exposure light EL fromthe optical integrator; a relay lens system; and a variable field stopthat sets an illumination region on the reticle R illuminated by theexposure light EL to be slit shaped; and the like (none are shown).Further, the illumination optical system IL illuminates a predeterminedillumination region on the reticle R with the exposure light EL, whichhas a uniform luminous flux intensity distribution.

Examples of light that can be used as the exposure light EL emitted fromthe illumination optical system IL include: deep ultraviolet light (DUVlight) such as KrF excimer laser light (248 nm wavelength), the brightlines (g, h, and i lines) in the ultraviolet region emitted from, forexample, a mercury lamp, and vacuum ultraviolet light (VUV light) suchas ArF excimer laser light (193 nm wavelength) and F₂ laser light (157nm wavelength). ArF excimer laser light is used in the presentembodiment.

The reticle stage RST supports the reticle R, is two dimensionallymovable in the plane perpendicular to the optical axis AX of theprojection optical system PL, i.e., in the XY plane, and is finelyrotatable in the θZ direction. A reticle stage drive apparatus RSTD(such as a linear motor), which is controlled by the control apparatusCONT, drives the reticle stage RST. A movable mirror 50 is provided onthe reticle stage RST. In addition, a laser interferometer 51 isprovided at a position opposing the movable mirror 50. Furthermore, thelaser interferometer 51 measures in real time the position in the twodimensional directions and the rotational angle of the reticle R on thereticle stage RST, and outputs these measurement results to the controlapparatus CONT. Furthermore, the control apparatus CONT drives thereticle stage drive apparatus RSTD based on the measurement results ofthe laser interferometer 51, and thereby positions the reticle R, whichis supported by the reticle stage RST.

The projection optical system PL projects the pattern AR of the reticleR onto the wafer W at a prescribed projection magnification β so as toexpose the wafer W, and has a plurality of optical elements thatincludes the optical element 2 provided at the tip part on the wafer Wside; in addition, these optical elements are supported by a lens barrelPK. In the present embodiment, the projection optical system PL is areduction system that has a projection magnification β of, for example,¼ or ⅕. Furthermore, the projection optical system PL may be an equalmagnification system or an enlargement system. In addition, the opticalelement 2 at the tip part of the projection optical system PL isdetachably (replaceably) provided to the lens barrel PK, and the liquidL of the immersion area AR2 contacts the optical element 2.

The optical element 2 is made of calcium fluorite. Because calciumfluorite has a strong affinity for water, the liquid L can adhere tosubstantially the entire surface of a liquid contact surface 2 a of theoptical element 2. Namely, because the liquid (water) L supplied has astrong affinity for the liquid contact surface 2 a of the opticalelement 2, the liquid contact surface 2 a of the optical element 2 andthe liquid L have strong adhesion characteristics, and therefore theoptical path between the optical element 2 and the wafer W can bereliably filled with the liquid L. Furthermore, the optical element 2may be made of silica glass, which also has a strong affinity for water.In addition, the liquid contact surface 2 a of the optical element 2 maybe given hydrophilic (lyophilic) treatment in order to further raise itsaffinity for the liquid L.

In addition, the lower surface (hereinbelow, referred to as a liquidcontact surface PKa) of the lens barrel PK, which surrounds and holdsthe optical element 2, is made of a material that is strongly lyophilic,e.g., anodized aluminum and the like, and has a strong affinity for theliquid L. Thereby, a gap between the wafer W and a lower surface PLa,which has the liquid contact surfaces 2a, PKa of the optical element 2and the lens barrel PK respectively, of the projection optical system PLcan be reliably filled with the liquid L.

In addition, an annular spare immersion area forming member 60 (notshown in FIG. 1) is fixed to a lower end part of the projection opticalsystem PL so that it surrounds the lens barrel PK. Furthermore, thespare immersion area AR3 is formed by supplying the liquid L between thewafer W and a part of the lower surface of the spare immersion areaforming member 60. Similar to the lens barrel PK, the spare immersionarea forming member 60 is made of a material that is strongly lyophilicand has a strong affinity for the liquid L. Thereby, the liquid Lprovided between the wafer W and the spare immersion area forming member60 is reliably held, which suppresses the leakage of liquid L to theoutside of the spare immersion area forming member 60.

Furthermore, supply ports 13 of the liquid supply mechanism 10 andrecovery ports 23 of the liquid recovery mechanism 20, these ports beingdiscussed later, are formed in the spare immersion area forming member60, and the liquid L of the immersion area AR2 and the spare immersionarea AR3 is supplied and recovered through the supply ports 13 and therecovery ports 23.

Furthermore, the spare immersion area forming member 60 may be formedfrom a member different from the lens barrel PK, as described in thepresent embodiment, and may be fixed to the lower end part of theprojection optical system PL, or it may be formed integrally with thelens barrel PK.

The wafer stage WST supports the wafer W and has a Z stage 52 that holdsthe wafer W via a wafer holder, an XY stage 53 that supports the Z stage52, and a base 54 that supports the XY stage 53. A wafer stage drivepart WSTD (such as a linear motor), which is controlled by the controlapparatus CONT, drives the wafer stage WST. Furthermore, driving the Zstage 52 controls the position of the wafer W held on the Z stage 52 inthe Z axial direction (the focus position) and in the θX and θYdirections. In addition, driving the XY stage 53 controls the positionof the wafer W in the X and Y directions (the position in the directionssubstantially parallel to the image plane of the projection opticalsystem PL). In other words, the Z stage 52 controls the focus positionand the inclination angle of the wafer W, and aligns the surface of thewafer W with the image plane of the projection optical system PL by anauto focus system and an auto leveling system; further, the XY stage 53positions the wafer W in the X axial direction and Y axial direction.Furthermore, the Z stage 52 and the XY stage 53 may be integrallyprovided.

A movable mirror 55 is provided on the wafer stage WST (the Z stage 52).In addition, a laser interferometer 56 is provided at a positionopposing the movable mirror 55. Furthermore, the laser interferometer 56measures in real time the position in the two dimensional directions aswell as the rotational angle of the wafer W on the wafer stage WST, andoutputs these measurement results to the control apparatus CONT.Furthermore, the control apparatus CONT drives the wafer stage drivepart WSTD based on the measurement results of the laser interferometer56, and thereby positions the wafer W supported on the wafer stage WST.

In addition, an auxiliary plate 57 is provided on the wafer stage WST (Zstage 52) so that it surrounds the wafer W. The auxiliary plate 57 has aflat surface that is at a height substantially the same as the surfaceof the wafer W, which is held by the wafer holder. Furthermore, there isa gap of approximately 1 to 2 mm between the edge of the wafer W and theauxiliary plate 57, but hardly any of the liquid L flows into that gapdue to the surface tension of the liquid L, and the auxiliary plate 57can hold the liquid L at the lower surface PLa of the projection opticalsystem PL, even when exposing the vicinity of the circumferential edgeof the wafer W.

The liquid supply mechanism 10 supplies the prescribed liquid L onto thewafer W, and has a liquid producing part 11 that is capable of supplyingthe liquid L, the plurality of supply ports 13 disposed proximate to thesurface of the wafer W, and a supply pipe 12 that connects the liquidproducing part 11 to each of the supply ports 13. Furthermore, theplurality of supply ports 13 is formed in the spare immersion areaforming member 60, which was discussed above. In addition, the liquidproducing part 11 has an ultrapure water apparatus that produces purewater (liquid L), a tank that stores the liquid L, a pressure pump, andthe like, and supplies the liquid L onto the wafer W through the supplypipe 12 and the supply ports 13.

Furthermore, among the various members that constitute the liquid supplymechanism 10, at least the member that distributes the liquid L is madeof a synthetic resin, e.g., polytetrafluoroethylene. It is therebypossible to suppress the inclusion of impurities in the liquid L.

Furthermore, the liquid supply operation of the liquid producing part 11is controlled by the control apparatus CONT, which can control theamount of the liquid supplied per unit of time to the wafer W by theliquid producing part 11.

The liquid recovery mechanism 20 recovers the liquid L on the wafer W,and has a liquid suction part 21 capable of suctioning the liquid L, aplurality of recovery ports 23 and recovery nozzles 24 disposedproximate to the surface of the wafer W, and a recovery pipe 22 thatconnects the liquid suction part 21 to each of the recovery ports 23 andrecovery nozzles 24. (Although not shown in FIG. 1, the recovery ports23 are also connected to the recovery pipe 22.) Furthermore, theplurality of recovery ports 23 is formed in the spare immersion areaforming member 60, which is discussed above. In addition, the liquidsuction part 21 has a suction apparatus, such as a vacuum pump, a tankthat stores the recovered liquid L, or the like, and recovers the liquidL on the wafer W by suction through the recovery ports 23 and therecovery pipe 22.

Furthermore, similar to the liquid supply mechanism 10, in order tosuppress the inclusion of impurities in the liquid L, among the variousmembers that constitute the liquid recovery mechanism 20, at least themember that distributes the liquid L is made of a synthetic resin, e.g.,polytetrafluoroethylene.

Furthermore, the liquid recovery operation of the liquid suction part 21is controlled by the control apparatus CONT, which can control theamount of liquid recovered per unit of time by the liquid suction part21.

FIGS. 2A and 2B are enlarged views that depict the details of thevicinity of the immersion area AR2, wherein FIG. 2A is a side crosssectional view that includes the projection optical system PL, and FIG.2B depicts the lower surface side of the projection optical system PL,viewed from the wafer stage WST side. In addition, FIG. 3A is anperspective view of the lower surface side of the projection opticalsystem PL, viewed from the wafer stage WST side.

As depicted in FIGS. 2A, 2B and 3A, the optical element 2 and part ofthe lens barrel PK that form the immersion area AR2 are disposed at thelower end part of the projection optical system PL.

In addition, the spare immersion area forming member 60 that forms thespare immersion area AR3 is disposed at the outer circumference of thelower end part of the .projection optical system PL. An annular groovepart 70 and an annular wall part 80 (annular protrusion), which isdisposed on the outer side of the groove part 70, are formed on theinner circumferential side of a lower surface 60 a of the spareimmersion area forming member 60.

The groove part 70 is formed so that it surrounds the lens barrel PK andsinks in the Z direction by a prescribed distance from the lower surfacePLa of the projection optical system PL.

The wall part (liquid holding part) 80 is provided so that it is uprightfrom a bottom surface 70 b of the groove part 70 toward the wafer W, andso that it is spaced apart at a prescribed spacing in the radialdirection from the lower surface PLa of the projection optical system PLthat forms the immersion area AR2, and so that it surrounds the lowersurface PLa of the projection optical system PL. Furthermore, the wallpart 80 is formed so that the distance between the wafer W and the lowersurface 80 a of the wall part 80 is substantially identical to thedistance between the wafer W and the lower surface PLa of the projectionoptical system PL. However, both distances may be different. Forexample, the distance between the wafer W and the lower surface 80 a ofthe wall part 80 may be set smaller than the distance between the waferW and the lower surface PLa of the projection optical system PL, andvice versa. Furthermore, it is preferable that the distance between thewafer W and the lower surface 80 a of the wall part 80 is as small aspossible. This is because the smaller the distance, the more reliablythe liquid L is held by the surface tension thereof, and the better theleakage of the liquid to the outside can be prevented. Nevertheless, thesmaller the distance between the wafer W and the lower surface 80 a ofthe wall part 80, the greater the possibility of interfering with thewafer W and the like; therefore, as depicted in the present embodiment,the lower surface 80 a of the wall part 80 may be formed so that it isat the substantially identical position (in the Z direction) as thelower surface PLa of the projection optical system PL, or the wall part80 may be made of an elastic material, such as rubber. In addition, thearea of the lower surface 80 a of the wall part 80 is set in accordancewith conditions, such as the amount of the liquid L held. For example,the larger the area of the lower surface 80a, the greater the surfacearea of contact with the liquid L, and the greater the amount of theliquid L that can be held. Furthermore, the lower surface 80 a is notnecessarily flat. For example, it may be hemispherical. This is becauseany shape is acceptable as long as the liquid L can be held by itssurface tension.

In addition, it is also possible to increase or decrease the amount ofthe liquid L that can be held by adjusting the spacing between theimmersion area AR2 and the wall part 80, i.e., by adjusting the width ofthe groove parts 70.

For example, depending on the amount of the liquid L to be held, thewidth of the lower surface 80 a may be set five times or more greaterthan the distance between the lower surface 80 a of the wall part 80 andthe wafer W. In addition, the width of the groove part 70 may be setfive times or more greater than the distance between the lower surface80 a of the wall part 80 and the wafer W. In this case, if the distancebetween the lower surface 80 a of the wall part 80 and the wafer W isset to 1 to 2 mm, then the width of the lower surface 80 a should be setto 5 to 10 mm or greater, and the width of the groove part 70 should beset to 5 to 10 mm or greater.

The supply ports 13, which are part of the liquid supply mechanism 10that supply the liquid L onto the wafer W, and the recovery ports 23,which are part of the liquid recovery mechanism 20 that recovers theliquid L on the wafer W, are formed at the bottom surface 70 b of thegroove part 70.

As depicted in FIG. 2B and FIG. 3A, the supply ports 13 are at thebottom surface 70 b of the groove part 70, and are formed as two archedslit holes along the outer circumference of the lens barrel PK of theprojection optical system PL on both sides of the wafer W in thescanning directions (the +X direction and the −X direction). Inaddition, as depicted in FIG. 2B and FIG. 3A, the recovery ports 23 areat the bottom surface 70 b of the groove part 70, and are formed assubstantially annular slit holes at the outer circumference of thesupply ports (liquid recovery parts) 13. The recovery ports 23 areformed substantially annular in order to recover, without any leakage,the liquid L on the wafer W. Furthermore, the bottom surface 70 b of thegroove part 70 wherein the recovery ports 23 are formed may be made of aporous body 25, as depicted in FIG. 3B. This is because, by recoveringthe liquid L through the porous body 25, it becomes difficult to suckgas (air) into the recovery pipe 22, and it is therefore possible toprevent the generation of vibrations in accordance with the intermixingof bubbles.

In addition, the porous body 25 may be formed around the entirecircumference of the bottom surface 70 b of the groove part 70, and theliquid L may be collected via the recovery ports 23 connected to thisporous body 25. At this time, if the liquid L is sucked in at a fixedpressure by, for example, the liquid recovery mechanism 20 (not shown inFIG. 9A and FIG. 9B, but refer to FIG. 1), which is connected to therecovery ports 23, then it is possible to prevent the outflow of theliquid L outside of a predetermined area because the liquid L iscontinually collected at the portion where it contacts the porous body25, even if the amount of the liquid L inside the spare immersion areaAR3 fluctuates and the contact area between the porous body 25 and theliquid L varies. Furthermore, because the recovery of the liquid L isperformed continually through the porous body 25, it becomes difficultfor gas to be sucked into the recovery pipe 22, and it is therefore alsopossible to prevent the generation of vibrations in accordance with theintermixing of gas.

Furthermore, the plurality of recovery nozzles (liquid recovery parts)24, which recover the liquid L, is also disposed at the outercircumference of the wall part 80. These recovery nozzles are for thepurpose of recovering the liquid L that leaks to the outer circumferenceside of the wall part 80, and to prevent problems with the exposureapparatus EX. The shape, arrangement, quantity, and the like of therecovery nozzles 24 can be suitably modified in accordance with theamount of the liquid leakage and the like.

Furthermore, by supplying the liquid L from the supply ports 13 onto thewafer W, a gap between the wafer W and the lower surface PLa of theprojection optical system PL, which constitutes the liquid contactsurfaces 2 a, PKa of the optical element 2 and the lens barrel PKrespectively, is filled with the liquid L, thereby forming the immersionarea AR2. Furthermore, the immersion area AR2 includes the projectionarea AR1 (see FIG. 2B) of the projection optical system PL, which is setto a rectangular shape wherein the longitudinal direction is the Y axialdirection (the non-scanning direction). As discussed above, because theliquid contact surfaces 2 a, PKa of the optical element 2 and the lensbarrel PK are made of a material that has a strong affinity for theliquid L, they closely contact the liquid L and hold the liquid L by thesurface tension thereof.

Furthermore, the liquid L supplied from the supply ports 13 onto thewafer W also flows into part of the area surrounded by the wall part 80,between the lower surface 60 a of the spare immersion area formingmember 60 and the wafer W, thereby filling this part with the liquid Land forming the spare immersion area AR3. Furthermore, it is not thecase that the entire outer circumferential area of the immersion areaAR2 is continually filled with the liquid, and the spare immersion areaAR3 is formed by filling a part thereof with the liquid L (refer to FIG.4).

Thus, because the groove part 70 is provided at the outer circumferenceof the immersion area AR2, and the wall part 80 is further provided tothe outer side thereof spaced apart by a prescribed gap, the spareimmersion area AR3, which further holds the liquid L, is formed at theouter circumference of the immersion area AR2.

Furthermore, the liquid L of the immersion area AR2 and the liquid L ofthe spare immersion area AR3 are in close contact, and the liquid L canalternate (be distributed) between the immersion area AR2 and the spareimmersion area AR3. This is because, similar to the optical element 2and the like, the wall part 80 and the groove part 70 are made of amaterial that has a strong affinity (lyophilic) for the liquid L, andtherefore the liquid L of the immersion area AR2 and the liquid L of thespare immersion area AR3 form a state wherein they are in continuouscommunication, without being spaced apart.

In addition, the periphery of the spare immersion area AR3 (the side notin contact with the immersion area AR2) transitions to a state whereinit contacts the gas (e.g., an inert gas, such as air or nitrogen gas)inside the space in which the wafer stage WST, the projection opticalsystem PL, and the like are installed.

The following explains the method of exposing the wafer W with the imageof the pattern AR of the reticle R by using the exposure apparatus EXdiscussed above, referencing the drawings.

FIG. 4 depicts an example of the shape of the liquid L disposed in theimmersion area AR2 and the spare immersion area AR3 at the start ofexposure. FIG. 5 depicts an aspect of the movement of the liquid L inthe immersion area AR2 and the spare immersion area AR3.

First, when the reticle R is loaded on the reticle stage RST, the waferW is loaded on the wafer stage WST, and the scanning exposure process isstarted, the control apparatus CONT operates the liquid supply mechanism10 and starts the operation of supplying the liquid onto the wafer W.When the liquid supply mechanism 10 is operated, the liquid L suppliedfrom the liquid producing part 11 is distributed through the supply pipe12, and then is simultaneously supplied onto the wafer W from the supplyports 13 formed on both sides of the bottom surface 70 b of the groovepart 70 of the spare immersion area forming member 60, in the scanningdirection. The liquid L supplied onto the wafer W flows along thesurface of the lens barrel PK and fills the area of the lower surfacePLa of the projection optical system PL, thereby forming the immersionarea AR2. Furthermore, after the immersion area AR2 is formed, theliquid L is continuously supplied and, as depicted in FIG. 4, fills partof the outer circumferential area of the immersion area AR2, therebyforming the spare immersion area AR3.

Furthermore, after forming the immersion area AR2 and the spareimmersion area AR3, the liquid recovery mechanism 20 is also operated,the amount of the liquid L supplied and the amount of the liquid Lrecovered are set substantially equal, or so that the supplied amount isslightly greater than the recovered amount, and that state ismaintained.

In so doing, the liquid L of, for example, an amount equal to at leastapproximately 10 to 20% of the liquid L in the immersion area AR2 isdisposed in the spare immersion area AR3 at the start of the exposure.

Next, after the various exposure conditions are set, prescribedpreparatory work, such as the reticle alignment using a reticlemicroscope, an off-axis alignment sensor, and the like (none are shown),the baseline measurement of an alignment sensor, and the like areperformed under the management of the control apparatus CONT.Subsequently, when the fme alignment (enhanced global alignment (EGA)and the like) of the wafer W using the alignment sensor is finished, thearray coordinates of a plurality of shot regions on the wafer W isderived.

When the preparatory work for exposing the wafer W is finished, thecontrol apparatus CONT continues to monitor the measurement values ofthe laser interferometer 56 on the wafer W side based on the alignmentresult, and instructs the wafer stage drive part WSTD to move the waferstage WST to an acceleration start position (scan start position) inorder to expose a first shot region of the wafer W.

Subsequently, the control apparatus CONT instructs the reticle stagedrive part RSTD and the wafer stage drive part WSTD to start scanningwith the reticle stage RST and the wafer stage WST in the X axialdirection; when the reticle stage RST and the wafer stage WST reachtheir respective target scanning speeds, the exposure light ELirradiates the pattern area of the reticle R, thereby starting thescanning exposure.

Furthermore, the different areas of the pattern area of the reticle Rare consecutively illuminated by the exposure light EL, and the scanningexposure of the first shot region on the wafer W is finished by thecompletion of the illumination of the entire surface of the patternarea. Thereby, the pattern AR of the reticle R is reduction-transferredonto the resist layer of the first shot region on the wafer W throughthe projection optical system PL and the liquid L.

When the scanning exposure of this first shot region is finished, thecontrol apparatus CONT moves the wafer stage WST in steps in the X and Yaxial directions, and moves it to the acceleration start position inorder to expose a second shot region. Namely, a stepping operation isperformed between the shots.

Furthermore, the second shot region is scanning-exposed, as discussedabove.

In so doing, the scanning exposure of a shot region on the wafer W andthe stepping operation in order to expose the next shot region areperformed repetitively, and the pattern AR of the reticle R is therebysequentially transferred onto all exposure target shot regions on thewafer W.

After the completion of the wafer W exposure process, the operation ofthe liquid supply mechanism 10 is stopped, the amount of the liquid Lrecovered by the liquid recovery mechanism 20 is increased, and all ofthe liquid L in the immersion area AR2 and the spare immersion area AR3is recovered.

Furthermore, after recovering the liquid L, the wafer W is replaced andthe exposure process is resumed for the new wafer W. By the repetitionof such a process, a plurality of wafers W is exposed.

As discussed above, when performing a scanning exposure, the exposureapparatus EX moves the wafer W, via the XY stage 53, with respect to theprojection optical system PL, in the +X direction (or the −X direction)at a speed (β·V (where β is the projection magnification), synchronizedto the movement of the reticle R in the −X direction (or +X direction)at a speed V. Furthermore, the scanning exposure and the subsequentstepping operation in order to expose the next shot region are performedrepetitively. Namely, by using the so-called step-and-scan system, thescanning exposure process is performed sequentially for each shot regionwhile moving the wafer W.

Thus, when the wafer W is moved in the X and Y directions with respectto the projection optical system PL, the lower surface PLa of theprojection optical system PL, i.e., the liquid L disposed in theimmersion area AR2, is dragged by the movement of the wafer W and beginsto move in the movement direction thereof. . In particular, the wafer Wmoves at a high speed (e.g., approximately 300 mm/s) during the scanningexposure, and the amount of movement of the liquid L therefore becomeslarge.

With a conventional exposure apparatus, if the liquid L moves togetherwith the wafer W, then the liquid L separates at part of the lowersurface PLa of the projection optical system PL (on the side opposite tothe movement direction of the wafer W), which changes the wavelength ofthe exposure light EL and creates a risk of an exposure failure.

Nevertheless, in the exposure apparatus EX of the present embodiment, aspare immersion area AR3 is further provided at the outer circumferenceof the immersion area AR2; consequently, as depicted in FIG. 5, if thewafer W moves, then the liquid L of the immersion area AR2 flows intothe spare immersion area AR3 in the movement direction of the wafer W.Simultaneously therewith, the liquid L in the spare immersion area AR3on the side opposite to the movement direction of the wafer W flows intothe immersion area AR2.

Namely, the spare immersion area AR3 functions like a spare tank for theimmersion area AR2 by collecting the liquid L that overflows from theimmersion area AR2 in accordance with the movement of the wafer W, aswell as by supplying the liquid L to the immersion area AR2. Thereby, ashortage of the liquid L in the immersion area AR2 can be replenished,and the immersion area AR2 can be continually filled with the liquid L.Furthermore, because the entire area where the spare immersion area AR3is formed, i.e., the area surrounded by the wall part 80, is notcompletely filled with the liquid L, the liquid L recovered from theimmersion area AR2 to the spare immersion area AR3 can be accumulatedinside the area surrounded by the wall part 80 without leaking to theouter side thereof.

Furthermore, when the movement direction of the wafer W reverses and thelike, the wafer W moves so that the liquid L collected in the spareimmersion area AR3 returns to the immersion area AR2, while the liquid Lin the immersion area AR2 returns to the spare immersion area AR3. Inaddition, even when the wafer W moves on back and forth in thenon-scanning direction, or when the movement in the scanning directionand the movement in the non-scanning direction are performedrepetitively, the liquid L likewise goes back and forth between theimmersion area AR2 and the spare immersion area AR3, and the immersionarea AR2 can thereby be continually filled with the liquid L.

Thus, by further providing the spare immersion area AR3 at the outercircumference of the immersion area AR2, it is possible to easily andreliably avoid a shortage of the liquid L in the immersion area AR2 inaccordance with the movement of the wafer W, and the immersion area AR2can be continually filled with the liquid L. In addition, even if themovement direction of the wafer W changes, the liquid L disposed in theimmersion area AR2 and the spare immersion area AR3 goes back and forththerebetween, and it is therefore possible to continually fill the areaof the lower surface PLa of the projection optical system PL with theliquid L, as well as to maintain a constant wavelength of the exposurelight EL. It is thereby possible to prevent an exposure failure.

Accordingly, it is no longer necessary, as with a conventional exposureapparatus, to perform a special process, such as controlling,independently for each supply port, the flow rate of the liquid Lsupplied from the plurality of supply ports in accordance with themovement direction, the speed, and the like of the wafer W, and it isthereby possible to reduce the burden on the control apparatus CONT andto reduce the equipment cost of the exposure apparatus EX.

Incidentally, the amount of the liquid L disposed in the immersion areaAR2 and the spare immersion area AR3 during the exposure process doesnot always need to be constant. In other words, the amount of the liquidL supplied from the liquid supply mechanism 10 may be identical to theamount of the liquid L recovered from the liquid recovery mechanism 20,or the amount supplied may be greater than the amount recovered. Forexample, the liquid L disposed in the spare immersion area AR3 at thestart of exposure may be an amount equal to approximately 10 to 20% ofthe amount of the liquid L in the immersion area AR2, the amount of theliquid L supplied to the spare immersion area AR3 during the exposureprocess may increase gradually, and, at the completion of the wafer Wexposure process, the spare immersion area AR3 may be completely filledwith the liquid L.

Thus, if the amount of the liquid L supplied can be made greater thanthe amount recovered, there is no longer a need to precisely control theamount supplied and the amount recovered so that they are substantiallyconstant in order to prevent leakage from the immersion area AR2 or ashortage of liquid therein, as is the case with a conventional exposureapparatus, which reduces the burden on the control apparatus CONT.

Accordingly, while ensuring that the amount of the liquid L supplied inthe exposure apparatus EX does not fall below the amount recovered,minimum flow rate control should be performed so that the increase inthe temperature of the liquid L in accordance with the exposure processis within a prescribed range, which can simplify the control (operation)of the exposure apparatus EX.

In addition, if the wafer W is damaged or the like, bubbles may begenerated in the liquid L when such is supplied onto that wafer W.Furthermore, when these bubbles reach the immersion area AR2 inaccordance with the movement of the wafer W, there is a possibility thatthey may affect the exposure. Nevertheless, according to the presentembodiment, if the bubbles are positioned on the outer side of the spareimmersion area AR3, then, even if the bubbles generated on the wafer Wmove toward the immersion area AR2 in accordance with the movement ofthe wafer W, the bubbles can be captured by the spare immersion areaAR3, which is positioned before the immersion area AR2. Consequently, itis possible to prevent the infiltration of the bubbles into theimmersion area AR2 and to avoid influence on the exposure.

As explained above, the lower surface PLa of the projection opticalsystem PL can be continually filled with the liquid L. Furthermore,because the liquid L is pure water, it can be easily obtained in largequantities at semiconductor fabrication plants and the like, and has anadvantage in that it does not adversely affect the photoresist on thewafer W, the optical elements (lenses), and the like. In addition, purewater does not adversely affect the environment and has an extremely lowimpurity content, and can therefore be expected to also serve thefunction of cleaning the front surface of the wafer W as well as thelower surface PLa of the projection optical system PL.

Further, because the refractive index n of (pure) water for the exposurelight EL that has a wavelength of approximately 193 nm is substantially1.47, the use of ArF excimer laser light (193 nm wavelength) as thelight source of the exposure light EL would shorten the wavelength onthe wafer W to 1/n, i.e., to approximately 131 nm, thereby obtaining ahigh resolution. Furthermore, because the depth of focus will increaseapproximately n times, i.e., approximately 1.47 times, that of in air,the numerical aperture of the projection optical system PL can befurther increased if it is preferable to ensure a depth of focusapproximately the same as that when used in air, and the resolution isalso improved from this standpoint.

Furthermore, the operating procedure described in the embodimentdiscussed above, as well as the shapes and combinations of theconstituent members and the like, are just examples, and it isunderstood that variations and modifications are possible based onprocess conditions, design requirements, and the like, without departingfrom the spirit and scope of the present invention. The presentinvention includes, for example, the following types of modifications.

Furthermore, FIG. 6 depicts a modified example of the groove part 70;FIGS. 7A and 7B depict modified examples of the wall part 80; FIGS. 8Aand 8B depict an example wherein supply nozzles 14 are disposed at theouter circumference of the wall part 80; and FIGS. 9A and 9B depict anexample wherein a plurality of wall parts 80 and the like is provided,which forms the spare immersion area AR3.

The amount of the liquid L disposed in the spare immersion area AR3 (theholding amount) is preferably adjusted by the speed of the movement ofthe wafer W. This is because the higher the movement speed of the waferW, the greater the amount of the liquid L that moves between theimmersion area AR2 and the spare immersion area AR3, which requires thata large amount of the liquid L be held by the spare immersion area AR3.

For example, if the movement speed of the wafer W in the non-scanningdirection is greater than the movement speed in the scanning direction,then the width of the groove part 70 in the non-scanning direction maybe set greater than the width in the scanning direction, as depicted inFIG. 6.

In addition, the present embodiment explained a case wherein the wallpart 80 has a shape that is annularly closed, but the present inventionis not limited thereto. As depicted in FIG. 7A, gaps may be formed inthe wall part 80. This is because there will be no problem with leakageof the liquid L as long as the gaps are of a size such that the liquid Lis held by its surface tension. Thus, if gaps are formed in the wallpart 80, the recovery nozzles 24 may be disposed in those gaps.

In addition, in place of a substantially annular wall part 80, aplurality of projection parts (liquid holding parts) 90, which aresubstantially annularly disposed, may be formed as depicted in FIG. 7B.This is because the liquid L can be held by its surface tension as longas the spacing between each of the projection parts. 90 is sufficientlynarrow.

In addition, the present embodiment explained a case wherein the supplyports 13 of the liquid supply mechanism 10, as well as the recoveryports 23 of the liquid recovery mechanism 20, are provided to the bottomsurface 70 b of the groove part 70, but the supply nozzles 14 and therecovery nozzles 24 may be disposed at the outer circumference of thewall part 80, as depicted in FIGS. 8A and 8B.

In addition, although not shown, the supply ports 13 and the recoveryports 23 may be provided to the lower surface 80 a of the wall part 80.

In addition, a plurality of groove parts 70 and wall parts 80 that formthe spare immersion area AR3 may be provided. This is because furtherproviding a plurality of wall parts 80 and the like, which hold theliquid L, at the outer circumference of one wall part 80, as depicted inFIGS. 9A and 9B, can increase the power of the spare immersion area AR3to hold the liquid L, and can prevent the leakage of the liquid to theouter side of the spare immersion area AR3.

In this case, setting a large width (increasing the surface area) of thelower surfaces 80 a of the wall parts 80, which are each disposedbetween mutually adjacent groove parts 70, is useful for holding theliquid L of the immersion area AR2.

At this time, there is no need to set the width of each lower surface 80a of the plurality of wall parts 80 so that they are equal; for example,the width of the lower surface of the inner side wall part may be setlarger, or vice versa.

Furthermore, there is no need to form the wall surface of each wall part80 so that it is perpendicular to the front surface of the wafer W, andeach wall surface may be a surface that is inclined so that itintersects the front surface of the wafer W.

Furthermore, as depicted in FIGS. 9A and 9B, the supply ports 13 thatsupply the liquid L may be provided to the bottom surface 70 b of theinnermost side groove part 70, while the recovery ports 23 that recoverthe liquid L may be provided to the bottom surface 70 b of the secondgroove part 70. Thus, the arrangement, quantity, and the like of thesupply ports 13 and the recovery ports 23 can be suitably modified.

In the embodiments discussed above, a lens is affixed as the opticalelement 2 at the tip of the projection optical system PL, and theoptical characteristics of the projection optical system PL, e.g.,aberrations (spherical aberration, coma aberration, and the like), canbe adjusted by this lens, but the optical element 2 can also be a planeparallel plate that is lower in cost than the lens.

Using a plane parallel plate as the optical element 2 is advantageousbecause, even if a substance (e.g., a silicon based organic substanceand the like), which lowers the uniformity of the transmittance of theprojection optical system PL, and the illumination intensity and theillumination intensity distribution of the exposure light EL on thewafer W during the transport, assembly, and adjustment of the exposureapparatus EX, adheres to that plane parallel plate, only the planeparallel plate needs to be replaced immediately before supplying theliquid L, and that replacement cost is lower compared with using a lensas the optical element that contacts the liquid L. In other words,because the surface of the optical element that contacts the liquid Lbecomes contaminated due to the adhesion of scattered particlesgenerated from the resist because of the irradiation using the exposurelight EL, and due to impurities in the liquid L, and the like, thatoptical element must be periodically replaced; however, by using a lowcost plane parallel plate for this optical element, the cost of thereplacement part is lower than a lens, less time is needed to effect thereplacement, and it is possible to suppress any increase in themaintenance cost (running cost) or decrease in throughput.

In addition, if high pressure is generated by the flow of the liquid Lbetween the wafer W and the optical element 2 at the tip of theprojection optical system PL, then instead of making the optical element2 replaceable, the optical element 2 may be firmly fixed by thatpressure so that it does not move.

In addition, although the embodiments discussed above explained a casewherein water is used as the liquid L, it may be a liquid other thanwater; for example, if the light source of the exposure light EL is anF₂ laser, then the F₂ laser light is not transmitted through water, soit would be acceptable to use as the liquid L a fluorine based fluid,such as fluorine based oil, that is capable of transmitting F₂ laserlight. In this case, the portion that contacts the liquid L ispreferably given lyophilic treatment by, for example, forming a thinfilm with a substance that has a low polarity molecular structure andcontains fluorine.

In addition, it is also possible to use as the liquid L one (e.g., cedaroil) that is transparent to the exposure light EL, has the highestpossible refractive index, and is stable with respect to the projectionoptical system PL and the photoresist provided on the surface of thewafer W. In this case as well, the surface is treated according to thepolarity of the liquid L used.

Furthermore, in the embodiments discussed above, an exposure apparatusis adopted that locally fills the liquid in the opening between theprojection optical system PL and the substrate P, but the presentinvention can also be adapted to a liquid immersion exposure apparatusthat moves a stage, which holds the substrate to be exposed, in a liquidbath, as well as to a liquid immersion exposure apparatus that forms aliquid bath that has a prescribed depth on the stage and holds thesubstrate therein. The structure and exposure operation of the immersionexposure apparatus that moves the stage that holds the substrate to beexposed in the liquid bath is disclosed in, for example, JapanesePublished Unexamined Patent Application No. H06-124873, and theimmersion exposure apparatus that forms a liquid bath of a prescribeddepth on the stage and holds the substrate therein is disclosed in, forexample, Japanese Published Unexamined Patent Application No. H10-303114and U.S. Pat. No. 5,825,043. As far as is permitted, the disclosures ofthe abovementioned publications and the U.S. Patent are each herebyincorporated by reference.

In addition, the present invention can also be adapted to an exposureapparatus that has an exposure stage that can hold and move a substrate,such as a wafer, to be processed, and a measurement stage, which isequipped with various measuring members, sensors, and the like, asdisclosed in Japanese Published Unexamined Patent Application No.11-135400. As far as is permitted, the disclosure of the abovementionedpublication is hereby incorporated by reference.

In addition, the exposure apparatus, wherein the liquid immersion methoddiscussed above is applied, is constituted to fill the space of theoptical path on the emission side of the terminal optical member of theprojection optical system PL with a liquid (pure water), and then exposethe wafer W (the substrate P), but the exposure apparatus may beconstituted so that it also fills the space of the optical path on theincident side of the terminal optical member of the projection opticalsystem with a liquid (pure water), as disclosed in the pamphlet ofInternational Publication WO2004/019128. As far as is permitted, thedisclosure of the above cited pamphlet is hereby incorporated byreference.

Furthermore, the numerical aperture NA of the projection optical systemmay become 0.9 to 1.3 if the liquid immersion method as discussed aboveis used. If the numerical aperture NA of such a projection opticalsystem increases, then random polarized light conventionally used as theexposure light may degrade imaging performance due to the polarizationeffect, and it is therefore preferable to use polarized illumination. Inthat case, it is better to illuminate with linearly polarized lightaligned in the longitudinal direction of the line pattern of theline-and-space pattern of the mask (the reticle), and to emit a largeamount of diffracted light of the S polarized light component (the TEpolarized light component), i.e., the polarized light directionalcomponent aligned in the longitudinal direction of the line pattern,from the pattern of the mask (the reticle). If the opening between theprojection optical system PL and the resist deposited on the surface ofthe substrate P is filled with a liquid, then the transmittance throughthe resist surface increases for the diffracted light of the S polarizedlight component (the TE polarized light component), which contributes tothe improvement of the contrast, compared with the case in which theopening between the projection optical system PL and the resistdeposited on the surface of the substrate P is filled with air (i.e., agas), and a high imaging performance can consequently be obtained evenif the numerical aperture NA of the projection optical system exceeds1.0. In addition, it is more effective to appropriately combine a phaseshift mask, the oblique incidence illumination method (particularly, thedipole illumination method) aligned in the longitudinal direction of theline pattern as disclosed in Japanese Published Unexamined PatentApplication No. H06-188169, and the like. As far as is permitted, thedisclosure of the abovementioned publication is hereby incorporated byreference.

In addition, if the substrate P is exposed with a fine line-and-spacepattern (e.g., a line-and-space of approximately 25 to 50 nm) using, forexample, an ArF excimer laser as the exposure light, as well as using aprojection optical system PL that has a reduction magnification ofapproximately ¼, then the structure of a mask M (e.g., the fineness ofthe pattern and the thickness of the chrome) causes the mask M to act asa polarizing plate due to the wave guide effect, and a larger amount ofdiffracted light of the S polarized light component (the TE polarizedlight component) in comparison with the diffracted light of the Ppolarized light component (the TM polarized light component), whichdecreases contrast, is emitted from the mask. In this case as well, itis preferable to use the linear polarized light illumination asdiscussed above; however, even if the mask M is illuminated with randompolarized light, a high resolution performance can be obtained by usinga projection optical system with a large numerical aperture NA of 0.9 to1.3. In addition, if exposing a substrate P with an ultrafmeline-and-space pattern of a mask M, then there is also a possibilitythat the P polarized light component (the TM polarized light component)will become greater than the S polarized light component (the TEpolarized light component) due to the wire grid effect; however, ifconditions are such that the substrate P is exposed with aline-and-space pattern larger than 25 nm, for example, an ArF excimerlaser as the exposure light, as well as using a projection opticalsystem that has a reduction magnification of approximately ¼, then agreater quantity of diffracted light of the S polarized light component(the TE polarized light component) than the diffracted light of the Ppolarized light component (the TM polarized light component) is emittedfrom the mask, and therefore a high imaging performance can be obtainedeven in the case of a projection optical system with a large numericalaperture NA of 0.9 to 1.3.

Furthermore, instead of just linear polarized light illumination (Spolarized light illumination) aligned in the longitudinal direction ofthe line pattern of the mask (the reticle), it is also effective tocombine the oblique incidence illumination method with the polarizedlight illumination method that linearly polarizes light in a directiontangential (circumferential) to a circle with the optical axis at thecenter. In particular, if the mask (reticle) pattern mixes line patternsextending in a plurality of differing directions, instead of a linepattern extending in a prescribed single direction, then by combiningthe zonal illumination method with the polarized light illuminationmethod that linearly polarizes light in a direction tangential to acircle having the optical axis at its center, it is possible to achievehigh imaging performance even if the numerical aperture NA of theprojection optical system is large.

In addition, the wafer W is not limited to a semiconductor wafer forfabricating semiconductor devices, and is also applicable to a glasssubstrate for a display device, a ceramic wafer for a thin film magnetichead, and the like.

In addition to a step-and-scan system scanning type exposure apparatus(scanning stepper) for performing scanning and exposure using thepattern of the reticle by synchronously moving the reticle and thewafer, the exposure apparatus EX can also be adapted to astep-and-repeat system projection exposure apparatus (stepper) forperforming exposure for the full pattern of the reticle with the reticleand the wafer in a stationary state and sequentially steps the wafer. Inaddition, the present invention can also be adapted to a step-and-stitchsystem exposure apparatus that partially and superimposedly transfers atleast two patterns onto the wafer.

In addition, the present invention can also be adapted to the twin stagetype exposure apparatus disclosed in Japanese Published UnexaminedPatent Application No. H10-163099 and the corresponding U.S. Pat. No.6,341,007, Japanese Published Unexamined Patent Application No.H10-214783 and the corresponding U.S. Pat. No. 6,341,007, PublishedJapanese Translation No. 2000-505958 of the PCT InternationalPublication and the corresponding U.S. Pat. No. 5,969 ,441, and thelike. Furthermore, as far as is permitted, the disclosures of theabovementioned publications are each hereby incorporated by reference.

The type of exposure apparatus EX is not limited to semiconductor devicefabrication exposure apparatuses that expose a wafer with the pattern ofa semiconductor device, but can also be widely adapted to exposureapparatuses for fabricating liquid crystal devices or displays, exposureapparatuses for fabricating thin film magnetic heads, imaging devices(CCDs), or reticles and masks, and the like.

In addition, if a linear motor is used in the wafer stage or the reticlestage, then either an air levitation type that uses an air bearing, or amagnetic levitation type that uses Lorentz's force or reactance force,may be used. In addition, the stages may be a type that moves along aguide, or may be a guideless type. Furthermore, if a planar motor isused as the drive apparatus for a stage, then either the magnet unit(permanent magnet) or the armature unit should be connected to thestage, and the other should be provided to the moving surface side(base) of the stage.

The reaction force generated by the movement of the wafer stage may bemechanically discharged to the floor (ground) using a frame member ofthe type recited in Japanese Published Unexamined Patent Application No.H08-166475 and the corresponding U.S. Pat. No. 5,528,118, so that themovement is not transmitted to the projection optical system PL. As faras is permitted, the disclosure of the abovementioned U.S. patent ishereby incorporated by reference.

The reaction force generated by the movement of the reticle stage may bemechanically discharged to the floor (ground) using a fraine member ofthe type recited in Japanese Published Unexamined Patent Application No.H08-330224 and the corresponding U.S. Pat. No. 5,874,820, so that themovement is not transmitted to the projection optical system PL. As faras is permitted, the disclosure of the abovementioned U.S. Patent ishereby incorporated by reference.

An exposure apparatus to which the present invention is adapted ismanufactured by assembling various subsystems, including eachconstituent element recited in the claims of the present application, sothat a prescribed mechanical accuracy, electrical accuracy, and opticalaccuracy are maintained. To ensure these various accuracies, adjustmentsare performed before and after this assembly, including an adjustment toachieve optical accuracy for the various optical systems, an adjustmentto achieve mechanical accuracy for the various mechanical systems, andan adjustment to achieve electrical accuracy for the various electricalsystems. The process of assembling the exposure apparatus from thevarious subsystems includes the mutual mechanical connection of thevarious subsystems, the wiring and connection of electrical circuits,the piping and connection of the atmospheric pressure circuit, and thelike. Naturally, before the process of assembling the exposure apparatusfrom the various subsystems, there is also the process of assemblingeach individual subsystem. When the process of assembling the exposureapparatus from the various subsystems is finished, a comprehensiveadjustment is performed to ensure the various accuracies of the exposureapparatus as a whole. Furthermore, it is preferable to manufacture theexposure apparatus in a clean room wherein the temperature, thecleanliness level, and the like, are controlled.

In addition, as shown in FIG. 10, a micro-device, such as asemiconductor device, is manufactured by: a step 201 that designs thefunctions and performance of the micro-device; a step 202 thatfabricates a mask (reticle) based on this design step; a step 203 thatfabricates a substrate, which is the base material of the device; anexposure processing step 204 wherein the exposure apparatus EX of theembodiments discussed above exposes the substrate with a pattern of themask; a device assembling step 205 (including a dicing process, abonding process, and a packaging process); an inspecting step 206; andthe like.

1. An exposure apparatus that forms an immersion area by supplying aliquid onto a part of a substrate, and forms a prescribed pattern on thesubstrate through the liquid, wherein a spare immersion area, which iscapable of holding part of the liquid on the substrate, is formed at anouter circumference of the immersion area.
 2. An exposure apparatusaccording to claim 1, comprising a projection optical system, wherein:the prescribed pattern is formed by exposing the substrate through theprojection optical system and the liquid positioned between theprojection optical system and the substrate; and when the projectionoptical system and the substrate move relatively to one another, part ofthe liquid of the immersion area moves to the spare immersion area, andpart of the liquid of the spare immersion area also moves to theimmersion area, in accordance with a direction of the relative movement.3. An exposure apparatus according to claim 1, wherein the liquid of thespare immersion area is held by a liquid holding part provided in amanner such that the liquid holding part is spaced apart by a prescribeddistance from the outer circumference of the immersion area.
 4. Anexposure apparatus according to claim 3, wherein the liquid holding partis provided at an outer circumference of a substantially annular groovepart formed in a lower surface of the projection optical system.
 5. Anexposure apparatus according to claim 3, wherein the liquid holding parthas a substantially annular wall part.
 6. An exposure apparatusaccording to claim 3, wherein the liquid holding part has a plurality ofprojection parts, which are disposed substantially annularly.
 7. Anexposure apparatus according to claim 3, wherein the liquid holding partis made of an elastic material.
 8. An exposure apparatus according toclaim 3, wherein a plurality of the liquid holding parts is provided. 9.An exposure apparatus according to claim 3, wherein a lyophilic area isformed in the liquid holding part.
 10. An exposure apparatus accordingto claim 2, wherein a liquid recovery part, which recovers the liquid,is provided at an outer circumference of the liquid holding part.
 11. Anexposure apparatus according to claim 4, wherein the liquid recoverypart, which recovers the liquid, is provided to a bottom surface of thegroove part.
 12. An exposure apparatus that exposes a substrate byfilling a gap between the substrate and a projection optical system witha liquid, and projecting a pattern image onto the substrate through theprojection optical system and the liquid, wherein: an immersion areathat includes a projection area of the projection optical system andthat is continually filled with the liquid during an exposure operation,and a spare immersion area provided to an outer circumference of theimmersion area are formed; and a first area wherein the liquid existsand a second area wherein the liquid does not exist are formed in thespare immersion area during the exposure operation, and positions of thefirst area and the second area inside the spare immersion area change inaccordance with the exposure operation.
 13. An exposure method forexposing a substrate by forming an immersion area by supplying a liquidonto part of a substrate, which includes a projection area of aprojection optical system, and projecting a pattern image onto thesubstrate through the projection optical system and the liquidpositioned between the projection optical system and the substrate, themethod comprising the step of disposing part of the liquid supplied ontothe substrate in a spare immersion area that is formed at an outercircumference of the immersion area.
 14. An exposure method according toclaim 13, wherein the step of disposing part of the liquid in the spareimmersion area is performed prior to exposure of the substrate.
 15. Anexposure method according to claim 13, further comprising the step ofsupplying and recovering the liquid to and from the immersion area andthe spare immersion area, wherein the amount of the liquid supplied tothe immersion area and the spare immersion area is greater than theamount of liquid recovered.
 16. An exposure apparatus that exposes asubstrate by forming an immersion area by supplying a liquid onto partof the substrate, and projecting a pattern image onto the substratethrough the liquid, wherein the immersion area has a first area thatincludes an area wherein the pattern image is projected; and a secondarea, which is proximate to the first area, wherein the liquid iscapable of moving to and from the first area.
 17. An exposure apparatusaccording to claim 16, wherein the second area is formed around thefirst area; and the amount of the liquid held by the second area changesin accordance with a direction in which the substrate moves during theexposure.
 18. An exposure apparatus according to claim 16, comprising: afirst liquid holding part that specifies a boundary between the firstarea and the second area; and a second liquid holding part thatspecifies the second area on a side where the second liquid holding partdoes not contact the first area.
 19. An exposure apparatus according toclaim 18, wherein at least one of the first liquid holding part and thesecond liquid holding part has a first surface that extends in adirection that intersects a surface of the substrate, and a secondsurface that contacts the first surface and opposes the substrate. 20.An exposure apparatus according to claim 18, wherein the first liquidholding part and the second liquid holding part are disposed so that thesecond area is formed around the first area, and so that the amount ofthe liquid held by the second area is specified in accordance with adirection in which the substrate moves during the exposure.
 21. Anexposure apparatus according to claim 18, wherein the liquid contacts agas in the second liquid holding part.
 22. An exposure apparatusaccording to claim 18, comprising a liquid holding member that isdisposed so that it opposes the substrate, wherein the liquid holdingmember includes the first liquid holding part and the second liquidholding part, and has a groove part formed in a surface opposing thesubstrate and between the first liquid holding part and the secondliquid holding part.
 23. An exposure apparatus according to claim 22,wherein a distance between the first liquid holding part and the secondliquid holding part is set to five times or more greater than a distancebetween the substrate and the liquid holding member.
 24. An exposureapparatus according to claim 22, wherein at least one of a liquid supplyport, which supplies the liquid to the immersion area, and a liquidrecovery part, which recovers the liquid from the immersion area, isprovided to the liquid holding member.
 25. An exposure apparatusaccording to claim 24, wherein at least one of the liquid supply portand the liquid recovery part is provided to the groove part.
 26. Anexposure apparatus that exposes a substrate by forming an immersion areaby supplying a liquid onto a part of the substrate, and projecting apattern image onto the substrate through the liquid, the apparatuscomprising: a liquid holding member for forming the immersion area,wherein the immersion area includes a first area, wherein the liquid iscontinually held during exposure, and a second area, which is capable ofmoving with respect to the liquid holding member during the exposure.27. An exposure apparatus according to claim 26, wherein the immersionarea is specified by a contact part between the liquid holding memberand the liquid, and the liquid of the second area contacts a gas at acircumference of the contact part.
 28. A device fabrication method thatincludes a lithographic process, wherein an exposure apparatus accordingto Claim 1, is used in the lithographic process.
 29. A devicefabrication method that includes a lithographic process, wherein anexposure method according to claim 13 is used in the lithographicprocess.